Spectroscopic characterization of a new Re(i) tricarbonyl complex with a thiosemicarbazone derivative: towards sensing and electrocatalytic applications

Author:

Souza Breno L.12345ORCID,Faustino Leandro A.12345ORCID,Prado Fernando S.12345,Sampaio Renato N.678910,Maia Pedro I. S.1112135ORCID,Machado Antonio Eduardo H.12345ORCID,Patrocinio Antonio Otavio T.12345ORCID

Affiliation:

1. Laboratory of Photochemistry and Materials Science

2. Institute of Chemistry

3. Universidade Federal de Uberlandia

4. Uberlandia

5. Brazil

6. Chemistry Division

7. Energy & Photon Sciences Directorate

8. Brookhaven National Laboratory

9. Upton

10. USA

11. Núcleo de Desenvolvimento de Compostos Bioativos (NDCBio)

12. Universidade Federal do Triângulo Mineiro

13. 38025-440 Uberaba

Abstract

A novel Re(i) complex with a thiosemicarbazone derivative is described and fully characterized. Its was further explored as CO2 reduction electrocatalyst, being the first complex with a thiosemicarbazone derivative applied to this goal.

Funder

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Alexander von Humboldt-Stiftung

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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