Electrocatalytic properties of a novel ruthenium(<scp>ii</scp>) terpyridine-based complex towards CO<sub>2</sub> reduction-Reference-Cited by-同舟云学术

Electrocatalytic properties of a novel ruthenium(ii) terpyridine-based complex towards CO₂ reduction

Published:2023 Issue:14 Volume:52 Page:4442-4455
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Faustino Leandro A.¹^ORCID,Machado Antonio E. H.¹²^ORCID,Maia Pedro I. S.³^ORCID,Concepcion Javier J.⁴^ORCID,Patrocinio Antonio Otavio T.¹^ORCID

Affiliation:

1. Laboratory of Photochemistry and Materials Science, Universidade Federal de Uberlândia - UFU, Av. João Naves de Ávila 212, 38400-902, Uberlândia, Minas Gerais, Brazil

2. Programa de Doutorado em Ciências Exatas e Tecnológicas, Universidade Federal de Catalão – UFCat, Av. Dr. Lamartine Pinto de Avelar 1120, Catalão, Goiás, Brazil

3. Núcleo de Desenvolvimento de Compostos Bioativos (NDCBio), Universidade Federal do Triângulo Mineiro, Av. Dr. Randolfo Borges 1400, 38025-440, Uberaba, Minas Gerais, Brazil

4. Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973-5000, USA

Abstract

A new Ru(ii) complex was synthesized, fully characterized and applied as electrocatalyst for CO2 reduction. The role of the reaction medium and the carboxylate ligand on the product selectivity was elucidated.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00121K

Reference65 articles.

1. Selective Generation of Formamides through Photocatalytic CO2Reduction Catalyzed by Ruthenium Carbonyl Compounds

2. Molecular quaterpyridine-based metal complexes for small molecule activation: water splitting and CO2 reduction

3. Elucidating the active sites for CO2 electroreduction on ligand-protected Au25 nanoclusters

4. Immobilising molecular Ru complexes on a protective ultrathin oxide layer of p-Si electrodes towards photoelectrochemical CO2 reduction

5. Electrocatalytic reduction of CO2 to CO by a mononuclear ruthenium(ii) complex

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