Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(i) carbonyl complex-Reference-Cited by-同舟云学术

Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(i) carbonyl complex

Published:2020 Issue:17 Volume:49 Page:5463-5470
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Eastwood Jonathan B.¹²³⁴^ORCID,Hammarback L. Anders¹²³⁴^ORCID,McRobie Matthew T.¹²³⁴,Clark Ian P.⁵⁶⁷⁴,Towrie Michael⁵⁶⁷⁴,Fairlamb Ian. J. S.¹²³⁴^ORCID,Lynam Jason M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of York

3. York

4. UK

5. Central Laser Facility

6. STFC Rutherford Appleton Laboratory

7. Didcot

Abstract

Photolysis of [Mn(C^N)(CO)₄] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)₃(N₂)].

Funder

University of York

Engineering and Physical Sciences Research Council

Syngenta International

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04878B

Reference47 articles.

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2. Ruthenium-catalysed oxidative conversion of ammonia into dinitrogen

3. Reactivity of Dinitrogen Bound to Mid‐ and Late‐Transition‐Metal Centers

4. E. A. Ison , Toward N-N Bond Cleavage: Synthesis and Reactivity of Group 7 Dinitrogen Complexes , in Transition Metal-Dinitrogen Complexes , Wiley-VCH , Weinheim , 2019 , ISBN: 978-3-527-34425-3

5. Cationic Manganese(I) Dihydrogen and Dinitrogen Complexes Derived from a Formally 16-Electron Complex with a Bis-Agostic Interaction, [Mn(CO)(Ph2PC2H4PPh2)2]+

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