Cationic Manganese(I) Dihydrogen and Dinitrogen Complexes Derived from a Formally 16-Electron Complex with a Bis-Agostic Interaction, [Mn(CO)(Ph2PC2H4PPh2)2]+
Author:
Affiliation:
1. Los Alamos National Laboratory Chemical Science and Technology Division MS-C346, Los Alamos, New Mexico 87545 Department of Chemistry, Yale University New Haven, Connecticut 06520
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja960499q
Reference25 articles.
1. Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals
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4. Transition Metal Complexation ofσ Bonds
5. Neutron structure and inelastic-neutron-scattering and theoretical studies of molybdenum complex Mo(CO)(H2)[(C6D5)2PC2H4P(C6D5)2]2.cntdot.4.5C6D6, a complex with an extremely low barrier to hydrogen rotation. Implications on the reaction coordinate for H-H cleavage to dihydride
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