Fac-to-mer isomerization triggers hydride transfer from Mn(<scp>i</scp>) complex fac-[(dppm)Mn(CO)3H]-Reference-Cited by-同舟云学术

Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)₃H]

Published:2022 Issue:32 Volume:58 Page:5017-5020
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Osipova Elena S.¹,Gulyaeva Ekaterina S.¹²,Kireev Nikolay V.¹,Kovalenko Sergey A.¹,Bijani Christian²,Canac Yves²^ORCID,Valyaev Dmitry A.²^ORCID,Filippov Oleg A.¹^ORCID,Belkova Natalia V.¹^ORCID,Shubina Elena S.¹^ORCID

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds (INEOS), Russian Academy of Sciences, 28 Vavilov str., GSP-1, B-334, Moscow, 119991, Russia

2. LCC-CNRS, Université de Toulouse, CNRS, 205 route de Narbonne 31077 Toulouse, Cedex 4, France

Abstract

Spectroscopic and theoretical studies revealed the crucial role of elusive Mn(i) meridional species in hydride transfer being potentially relevant for Mn-catalyzed hydrogenation-type processes.

Funder

Russian Science Foundation

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00999D

Reference61 articles.

1. Selective Catalytic Hydrogenations of Nitriles, Ketones, and Aldehydes by Well-Defined Manganese Pincer Complexes

2. Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study

3. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

4. Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions

5. Advancements in multifunctional manganese complexes for catalytic hydrogen transfer reactions

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Air-Stable Arene Manganese Complexes as Catalysts for the Syngas-Assisted Direct Reductive Amination, Cyanation of Aldehyde, and CO₂ Fixation by Epoxide with High Functional Groups Tolerance;The Journal of Organic Chemistry;2024-06-29

2. Impact of the Methylene Bridge Substitution in Chelating NHC‐Phosphine Mn(I) Catalyst for Ketone Hydrogenation;Chemistry – A European Journal;2024-02-28

3. Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation;Chemical Science;2024

4. C–Cl Bond Activation at Rotated vs Unrotated Dinuclear Site Related to [FeFe]-Hydrogenases;Inorganic Chemistry;2023-12-04

5. Basicity and Hydride-Donating Ability of Palladium(II) Hydride Complex with Diarylamido-bis-phosphine Pincer Ligand;Russian Journal of Inorganic Chemistry;2023-09