Biicosahedral metallaboranes: aromaticity in metal derivatives of three-dimensional analogues of naphthalene-Reference-Cited by-同舟云学术

Biicosahedral metallaboranes: aromaticity in metal derivatives of three-dimensional analogues of naphthalene

Published:2016 Issue:17 Volume:18 Page:11707-11710
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Attia Amr A. A.¹²³⁴⁵,Lupan Alexandru¹²³⁴⁵,Bruce King R.⁶⁷⁸⁹

Affiliation:

1. Department of Chemistry

2. Faculty of Chemistry and Chemical Engineering

3. Babeş-Bolyai University

4. Cluj-Napoca

5. Romania

6. Department of Chemistry and Center for Computational Quantum Chemistry

7. University of Georgia

8. Athens

9. USA

Abstract

The CpM units in the biicosahedral CpNiB₂₀H₁₇ and CpCoCB₁₉H₁₇ structures energetically prefer to be located at a meta vertex of the biicosahedron. Similar biicosahedral CpFeB₂₀H₁₇ structures are found with an agostic hydrogen atom bridging an Fe–B edge.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP05708F

Reference26 articles.

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3. Three-dimensional aromaticity of polyhedral boranes

4. A new model of structure and bonding in the boron hydrides

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