Palladium-promoted sulfur atom migration on carboranes: facile B(4)−S bond formation from mononuclear Pd-B(4) complexes-Reference-Cited by-同舟云学术

Palladium-promoted sulfur atom migration on carboranes: facile B(4)−S bond formation from mononuclear Pd-B(4) complexes

Published:2017-08-21 Issue:4 Volume:90 Page:607-616
ISSN:1365-3075
Container-title:Pure and Applied Chemistry
language:en
Short-container-title:

Author:

Wang Yin-Ping¹,Lin Yue-Jian¹,Jin Guo-Xin²

Affiliation:

1. Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials , Department of Chemistry , Fudan University , Shanghai 200433 , China

2. Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials , Department of Chemistry , Fudan University , Shanghai 200433 , China , Phone: +86 21 65643776, Fax: +86 21 65641740

Abstract

Abstract For the first time, carborane complexes containing a B(4)–S bond were obtained directly by heating mononuclear Pd-B(4)-bound carborane complexes. A possible mechanism involved in sulfur atom migration is presented in which the leaving group, pyridine, benzyl isocyanide or PPh3, is demonstrated to be the trigger of the reaction process. In this work, efficient routes are developed through one-pot reactions to prepare B(4)-S carborane derivatives.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/pac-2017-0609/pdf

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