Photoredox-mediated N-centered radical addition/semipinacol rearrangement for the convenient synthesis of β-amino (spiro)cyclic ketones-Reference-Cited by-同舟云学术

Photoredox-mediated N-centered radical addition/semipinacol rearrangement for the convenient synthesis of β-amino (spiro)cyclic ketones

Published:2021 Issue:15 Volume:8 Page:4224-4229
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ma Tian-Cong¹²³⁴⁵,Yao Sheng¹²³⁴⁵,Qiao Ming-Ming¹²³⁴⁵,Yuan Fan¹²³⁴⁵,Shi De-Qing¹²³⁴⁵^ORCID,Xiao Wen-Jing¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Pesticide & Chemical Biology

2. Ministry of Education

3. College of Chemistry

4. Central China Normal University

5. Wuhan

Abstract

A photoredox-mediated N-centered radical addition/semipinacol rearrangement cascade of cycloalkanol-substituted 1H-indenes or styrenes with N-arylsulfonyl protected 1-aminopyridinium salts for the efficient synthesis of β-amino (spiro)cyclic ketones is presented.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00543J

Reference65 articles.

1. Asymmetric Synthesis of Cyclic cis-β-Amino Acid Derivatives Using Sulfinimines and Prochiral Weinreb Amide Enolates

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4. Evaluation of some Mannich bases of cycloalkanones and related compounds for cytotoxic activity

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