Catalytic enantioselective synthesis of chiral spirocyclic 1,3-diketones via organo-cation catalysis-Reference-Cited by-同舟云学术

Catalytic enantioselective synthesis of chiral spirocyclic 1,3-diketones via organo-cation catalysis

Published:2021 Issue:85 Volume:57 Page:11233-11235
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Xiao-Yan¹,Shao Ya-Ping¹,Guo Bao-Kuan¹,Zhang Kun²,Zhang Fu-Min¹^ORCID,Zhang Xiao-Ming¹^ORCID,Tu Yong-Qiang¹^ORCID

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China

2. School of Biotechnology and Health Sciences, Wuyi University, Jiangmen, Guangdong, 529020, P. R. China

Abstract

Herein, an SPA-triazolium bromide catalyzed asymmetric transannular C-acylation of enol lactones is described, providing a novel approach to access chiral spirocyclic 1,3-diketones.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC05205E

Reference49 articles.

1. Novel Spiro Phosphinite Ligands and Their Application in Homogeneous Catalytic Hydrogenation Reactions

2. Spiro Skeletons: A Class of Privileged Structure for Chiral Ligand Design

3. Spiro[4,4]-1,6-Nonadiene-Based Diphosphine Oxides in Lewis Base Catalyzed Asymmetric Double-Aldol Reactions

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5. Metabolites with a Novel C30 Backbone from Marine Ciliates

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