Alternative anodes for Na–O2 batteries: the case of the Sn4P3 alloy

Author:

Gómez-Cámer Juan Luis1,Ruiz de Larramendi Idoia2ORCID,Enterría Marina1,Lozano Iñigo12,Acebedo Begoña1,Bordeau Domitille1ORCID,Ortiz-Vitoriano Nagore13

Affiliation:

1. Center for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Parque Tecnológico de Álava, Albert Einstein 48, 01510 Vitoria-Gasteiz, Spain

2. Departamento de Química Orgánica e Inorgánica, Universidad del País Vasco (UPV/EHU), P. O. Box 664, 48080 Bilbao, Spain

3. Ikerbasque, Basque Foundation for Science, María Díaz de Haro 3, 48013 Bilbao, Spain

Abstract

Formation of sodium superoxide on the anode evidences the existence of O2/O2 crossover processes. Sn4P3 alloy provides greater stability and less surface reactivity than metallic Na anode.

Funder

Ministerio de Economía y Competitividad

European Regional Development Fund

Eusko Jaurlaritza

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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