Is a transition metal–silicon quadruple bond viable?-Reference-Cited by-同舟云学术

Is a transition metal–silicon quadruple bond viable?

Published:2021 Issue:16 Volume:23 Page:9660-9662
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kalita Amlan J.¹²³⁴⁵,Rohman Shahnaz S.¹²³⁴⁵,Kashyap Chayanika¹²³⁴⁵,Ullah Sabnam S.¹²³⁴⁵,Baruah Indrani¹²³⁴⁵,Mazumder Lakhya J.¹²³⁴⁵,Sahu Prem P.¹²³⁴⁵,Guha Ankur K.¹²³⁴⁵^ORCID

Affiliation:

1. Advanced Computational Chemistry Centre

2. Department of Chemistry

3. Cotton University

4. Panbazar

5. Guwahati

Abstract

Quadruple bonding in heavier main group elements is not known albeit having four valence orbitals accessible for bonding.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00598G

Reference30 articles.

1. Metal-Metal Bonding in [Re2X8]2- Ions and Other Metal Atom Clusters

2. Building a Quintuple Bond

3. Quantum chemical calculations show that the uranium molecule U2 has a quintuple bond

4. The six-bond bound

5. Origin of Trans-Bent Geometries in Maximally Bonded Transition Metal and Main Group Molecules

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