Synthesis and a combined experimental/theoretical structural study of a comprehensive set of Pd/NHC complexes witho-,m-, andp-halogen-substituted aryl groups (X = F, Cl, Br, CF3)-Reference-Cited by-同舟云学术

Synthesis and a combined experimental/theoretical structural study of a comprehensive set of Pd/NHC complexes witho-,m-, andp-halogen-substituted aryl groups (X = F, Cl, Br, CF₃)

Published:2023 Issue:13 Volume:52 Page:4122-4135
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pankov Roman O.¹^ORCID,Prima Darya O.¹^ORCID,Kostyukovich Alexander Yu.¹^ORCID,Minyaev Mikhail E.¹^ORCID,Ananikov Valentine P.¹^ORCID

Affiliation:

1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospekt 47, Moscow, 119991, Russia

Abstract

A complete series of free NHC ligands and Pd/NHC complexes with –F, –Cl, –Br, and –CF3substituents at theo-,m-, andp-positions of the aryl ring were synthesized and characterized. An increase of catalytic activity was observed in the Mizoroki–Heck reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03665G

Reference64 articles.

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