Synthesis and comparative study of (NHCF)PdCl2Py and (NHCF)Ni(Cp)Cl complexes: investigation of the electronic properties of NHC ligands and complex characteristics-Reference-Cited by-同舟云学术

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Synthesis and comparative study of (NHC_F)PdCl₂Py and (NHC_F)Ni(Cp)Cl complexes: investigation of the electronic properties of NHC ligands and complex characteristics

Published:2024 Issue:30 Volume:53 Page:12503-12518
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pankov Roman O.¹,Tarabrin Ignatii R.¹²,Son Alexandra G.³^ORCID,Minyaev Mikhail E.¹^ORCID,Prima Darya O.¹^ORCID,Ananikov Valentine P.¹^ORCID

Affiliation:

1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospekt 47, Moscow, 119991, Russia

2. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119991, Russia

3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russia

Abstract

Nickel and palladium NHC complexes with fluorine substituents have been synthesized. Their electronic parameters, including σ-donation and π-acceptance, were evaluated, considering the position and number of substituents.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01304B

Reference59 articles.

1. A stable crystalline carbene

2. Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes

3. Hydration reactions catalyzed by transition metal–NHC (NHC = N-heterocyclic carbene) complexes

4. NHC-based pincer ligands: carbenes with a bite

5. Coordination Versatility of NHC-metal Topologies in Asymmetric Catalysis: Synthetic Insights and Recent Trends

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