DFT investigation of the ring contraction reaction of (η4-1,2-disilacyclohexadiene)iron tricarbonyls: a crucial intramolecular Si–Si bond activation-Reference-Cited by-同舟云学术

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DFT investigation of the ring contraction reaction of (η4-1,2-disilacyclohexadiene)iron tricarbonyls: a crucial intramolecular Si–Si bond activation

Published:2016 Issue:4 Volume:3 Page:480-485
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lin Changzhi¹²³⁴,Liu Qian⁵⁶⁷⁸,Zhang Yang⁹¹⁰¹¹¹²,Liu Jie⁹¹⁰¹¹¹²,Zheng Chenggang¹²³⁴

Affiliation:

1. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development

2. Petroleum Exploration and Production Research Institute

3. Beijing 100083

4. China

5. Department of Chemical and Materials Engineering

6. University of Alberta

7. Edmonton

8. Canada

9. Department of Chemistry

10. Nankai University

11. Tianjin 300071

12. People's Republic of China

Abstract

The ring contraction reaction mechanism of (η⁴-1,2-disilacyclohexadiene)iron tricarbonyls: crucial intramolecular Si–Si bond activation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QO/C5QO00402K

Reference50 articles.

1. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

2. SiSi and SiO Bond Activation at Platinum: Stepwise Formation of a SiH3Complex

3. Si–H and Si–Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes

4. Activation of Si–Si and Si–H bonds at Pt: a catalytic hydrogenolysis of silicon–silicon bonds

5. Activation of the Si-Si Bond by Transition Metal Complexes

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1. Oxidation of Pd(ii) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view;Dalton Transactions;2021

2. Computational study on NHC-catalyzed enantioselective and chemoselective fluorination of aliphatic aldehydes;Organic Chemistry Frontiers;2017

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