Oxidation of Pd(ii) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view-Reference-Cited by-同舟云学术

Oxidation of Pd(ii) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view

Published:2021 Issue:22 Volume:50 Page:7656-7666
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Jing¹²³⁴,Liu Shihan⁵⁶⁷⁸⁴,Zhang Tao⁹¹⁰¹¹¹²,Liu Tao¹²³⁴^ORCID,Lan Yu⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Department of Chemistry and Chemical Engineering

2. Jining University

3. Qufu 273155

4. P. R. China

5. School of Chemistry and Chemical Engineering

6. and Chongqing Key Laboratory of Theoretical and Computational Chemistry

7. Chongqing University

8. Chongqing 400030

9. Green Catalysis Center

10. and College of Chemistry Zhengzhou University Zhengzhou

11. Henan 450001

12. China

Abstract

DFT calculations were employed to study the mechanism of the Pd-catalyzed disilylation reaction of aryl halides, accompanying the discussion of the oxidizing ability of disilane and aryl halides.

Funder

National Natural Science Foundation of China

Science and Technology Innovation Talents in Universities of Henan Province

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00399B

Reference127 articles.

1. A Mild and Ligand-Free Ni-Catalyzed Silylation via C–OMe Cleavage

2. Photoinduced Formation of Hybrid Aryl Pd-Radical Species Capable of 1,5-HAT: Selective Catalytic Oxidation of Silyl Ethers into Silyl Enol Ethers

3. Organosilicon Molecules with Medicinal Applications

4. Palladium-Catalyzed Remote meta-Selective C–H Bond Silylation and Germanylation

5. Recent advances in C–Si bond activation via a direct transition metal insertion

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