Palladium-catalyzed disilylation of ortho-halophenylethylenes enabled by 2-pyridone ligand

Author:

Zhu Bin-Bin1ORCID,Zhang Shu-Sheng2ORCID,Fu Jian-Guo2ORCID,Lin Guo-Qiang21,Feng Chen-Guo21ORCID

Affiliation:

1. CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, China

2. The Research Center of Chiral Drugs, Innovation Research Institute of Traditional Chinese Medicine, Shanghai University of Traditional Chinese Medicine, Shanghai 201203, China

Abstract

A palladium-catalyzed disilylation reaction of ortho-halophenylethylenes has been developed with very low catalyst loadings and excellent yields.

Funder

Shanghai Municipal Education Commission

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Shanghai Science and Technology Development Foundation

Shanghai Municipal Health Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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