Polyoxometalate steric hindrance driven chirality-selective separation of subnanometer carbon nanotubes

Author:

Yang Xusheng1ORCID,Zhu Chao1,Zeng Lianduan23,Xue Weiyang1ORCID,Zhang Luyao1,Zhang Lei1,Zhao Kaitong1,Lyu Min4,Wang Lei1,Zhang Yuan-Zhu1ORCID,Wang Xiao2ORCID,Li Yan456ORCID,Yang Feng1ORCID

Affiliation:

1. Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China

2. Shenzhen Key Laboratory of Nanobiomechanics, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

3. Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215000, China

4. Beijing National Laboratory for Molecular Science, Key Laboratory for the Physics and Chemistry of Nanodevices, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

5. Peking University Shenzhen Institute, Shenzhen 518057, China

6. PKU-HKUST ShenZhen-HongKong Institution, Shenzhen 518057, China

Abstract

We develop a cluster steric hindrance strategy by assembling polyoxometalates on subnanometer single-walled carbon nanotubes (SWCNTs) and demonstrate the selective separation of single-chirality (6,5) SWCNTs via polymer extraction.

Funder

National Natural Science Foundation of China

Shenzhen Fundamental Research Program

Natural Science Foundation of Guangdong Province

Guangdong Provincial Key Laboratory Of Catalysis

National Key Research and Development Program of China

Beijing National Laboratory for Molecular Sciences

Southern University of Science and Technology

Nanjing University of Aeronautics and Astronautics

Shenzhen Institutes of Advanced Technology Innovation Program for Excellent Young Researchers

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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