Oxidative coupling of methane over Mo–Sn catalysts

Author:

Yan Lina12,Zhang Junfeng1ORCID,Gao Xiujuan13,Song Faen1,Wang Xiaoxing1,Zhang Tao1,Liu Xiaoyan4,Meng Xianghai2,Zhang Qingde15ORCID,Han Yizhuo1ORCID,Tan Yisheng1ORCID

Affiliation:

1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

2. China University of Petroleum, Beijing 102249, China

3. University of Chinese Academy of Sciences, Beijing 100049, China

4. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

5. Dalian National Laboratory for Clean Energy, CAS, Dalian 116023, China

Abstract

The selectivity of C2 hydrocarbons reached 98.1%, along with the methane conversion of 8.6% over Mo1Sn3 catalyst. The deep oxidation of methane to CO2 was significantly inhibited due to the moderately strong basic sites and reactive oxygen species.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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