Enhancing catalytic activity of pyridines via para-iminophosphorano substituents-Reference-Cited by-同舟云学术

Enhancing catalytic activity of pyridines via para-iminophosphorano substituents

Published:2021 Issue:42 Volume:19 Page:9167-9171
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Richard Nicholas A.¹^ORCID,Charlton Grant D.¹,Dyker C. Adam¹^ORCID

Affiliation:

1. Department of Chemistry, University of New Brunswick, Fredericton, New Brunswick, E3B 5A3, Canada

Abstract

Pyridine organocatalysts featuring 4-iminophosphorano substituents (R3PN–) are easily accessible, predictably tunable, and can surpass the activity of amino-substituted derivatives in the acylation of tertiary alcohols.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01630J

Reference58 articles.

1. 4-Dialkylaminopyridines as Highly Active Acylation Catalysts. [New synthetic method (25)]

2. Nucleophilic Catalysis by 4-(Dialkylamino)pyridines Revisited?The Search for Optimal Reactivity and Selectivity

3. Novel Amine Chemistry Based on DMAP-Catalyzed Acylation

4. 4-Dialkylaminopyridines: super acylation and alkylation catalysts

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