Electron-rich pyridines with para-N-heterocyclic imine substituents: ligand properties and coordination to CO2, SO2, BCl3 and PdII complexes-Reference-Cited by-同舟云学术

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Electron-rich pyridines with para-N-heterocyclic imine substituents: ligand properties and coordination to CO₂, SO₂, BCl₃ and Pd^II complexes

Published:2024 Issue:28 Volume:53 Page:11876-11883
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Franzen Jonas H.¹,Wilm Lukas F. B.²,Rotering Philipp¹,Wurst Klaus¹,Seidl Michael¹,Dielmann Fabian¹^ORCID

Affiliation:

1. Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria

2. Institut für Anorganische und Analytische Chemie, Universität Münster Corrensstrasse 30, 48149 Münster, Germany

Abstract

N-heterocyclic imine groups significantly increase the donor strength of pyridines and their propensity to form complexes with Lewis acids.

Funder

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01399A

Reference82 articles.

1. N,N-Dimethyl-4-pyridinamine, a Very Effective Acylation Catalyst

2. 4-Dialkylaminopyridines as Highly Active Acylation Catalysts. [New synthetic method (25)]

3. Aminopyridines as acylation catalysts for tertiary alcohols

4. Nucleophilic Catalysis by 4-(Dialkylamino)pyridines Revisited?The Search for Optimal Reactivity and Selectivity

5. 4-Dialkylaminopyridines: super acylation and alkylation catalysts

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