Electrosynthesis of iminophosphoranes and applications in nickel catalysis

Author:

Mdluli Velabo1ORCID,Lehnherr Dan1ORCID,Lam Yu-hong2ORCID,Chaudhry Mohammad T.3ORCID,Newman Justin A.3ORCID,DaSilva Jimmy O.3ORCID,Regalado Erik L.3ORCID

Affiliation:

1. Process Research and Development, Merck & Co., Inc., Rahway, New Jersey 07065, USA

2. Modeling and Informatics, Merck & Co., Inc., Rahway, New Jersey 07065, USA

3. Analytical Research and Development, Merck & Co., Inc., Rahway, New Jersey 07065, USA

Abstract

N-Cyano iminophosphoranes are synthesized using electrochemistry and evaluated as ligands in various nickel-catalysed reactions. The electronic and structural properties of these ligands were studied both computationally and experimentally.

Funder

Merck

Publisher

Royal Society of Chemistry (RSC)

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