Role of keto–enol tautomerization in a chiral phosphoric acid catalyzed asymmetric thiocarboxylysis of meso-epoxide: a DFT study-Reference-Cited by-同舟云学术

Role of keto–enol tautomerization in a chiral phosphoric acid catalyzed asymmetric thiocarboxylysis of meso-epoxide: a DFT study

Published:2015 Issue:45 Volume:13 Page:10981-10985
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ajitha Manjaly J.¹²³⁴,Huang Kuo-Wei¹²³⁴

Affiliation:

1. KAUST Catalysis Center and Division of Physical Science and Engineering

2. King Abdullah University of Science and Technology

3. Thuwal 23955-6900

4. Saudi Arabia

Abstract

The mechanism of a chiral phosphoric acid catalyzed thiocarboxylysis of meso-epoxide was investigated by density functional theory (DFT) calculations (M06-2X).

Funder

King Abdullah University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01473E

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