Identifying the true origins of selectivity in chiral phosphoric acid catalyzed N-acyl-azetidine desymmetrizations-Reference-Cited by-同舟云学术

Identifying the true origins of selectivity in chiral phosphoric acid catalyzed N-acyl-azetidine desymmetrizations

Published:2021 Issue:47 Volume:12 Page:15662-15672
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Champagne Pier Alexandre¹^ORCID

Affiliation:

1. Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, NJ, USA

Abstract

The origins of selectivity in azetidine desymmetrizations have been determined computationally. Comparison of structures with model and full catalysts provided key details missed by typical analyses of the stereodetermining transition structures.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04969K

Reference92 articles.

1. Asymmetric Catalysis Special Feature Part I: Asymmetric catalysis: An enabling science

2. I.Ojima , Catalytic asymmetric synthesis , John Wiley & Sons , Hoboken, NJ , 2010

3. Theory and Modeling of Stereoselective Organic Reactions

4. How reliable are DFT transition structures? Comparison of GGA, hybrid-meta-GGA and meta-GGA functionals

5. Theory and Modeling of Asymmetric Catalytic Reactions

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. First-Principles Characterization of Noncovalent Interactions in the Enantioselective Oxetane Ring Opening via SPHENOL-Based Chiral Phosphoric Acid Catalyst;The Journal of Organic Chemistry;2024-08-15

2. Quinquevalent phosphorus acids;Organophosphorus Chemistry;2024-02-21

3. %V_Bur index and steric maps: from predictive catalysis to machine learning;Chemical Society Reviews;2024

4. Visible-Light-Driven [2 + 2] Photocycloaddition for Constructing Dimers of N,N′-Diacyl-1,4-dihydropyrazines: Experimental and Theoretical Investigation;The Journal of Organic Chemistry;2023-09-07

5. Role of Chiral Skeleton in Chiral Phosphoric Acids Catalyzed Asymmetric Transfer Hydrogenation: A DFT Study;Catalysts;2023-01-03