Unravelling the mechanism of the organocatalyzed aminolytic kinetic resolution of α-nitroepoxides: a theoretical study-Reference-Cited by-同舟云学术

Unravelling the mechanism of the organocatalyzed aminolytic kinetic resolution of α-nitroepoxides: a theoretical study

Published:2020 Issue:5 Volume:10 Page:1422-1430
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Capobianco Amedeo¹²³⁴^ORCID,Meninno Sara¹²³⁴^ORCID,Lattanzi Alessandra¹²³⁴^ORCID

Affiliation:

1. Dipartimento di Chimica e Biologia “A. Zambelli”

2. Università di Salerno

3. I-84084 Fisciano

4. Italy

Abstract

The mechanism of the aminolytic kinetic resolution of 2-methyl-2-nitro-3-phenyl oxirane with aniline in the presence of Takemoto's catalyst is disclosed by way of DFT calculations.

Funder

Ministero dell'Istruzione, dell'Università e della Ricerca

Università degli Studi di Salerno

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/C9CY01800J

Reference52 articles.

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4. α-Nitro Epoxides in Organic Synthesis: Development of a One-Pot Organocatalytic Strategy for the Synthesis of Quinoxalines

5. Nitroepoxides as Versatile Precursors to 1,4-Diamino Heterocycles

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