Characterization and chemical reactivity of room-temperature-stable MnIII–alkylperoxo complexes-Reference-Cited by-同舟云学术

Characterization and chemical reactivity of room-temperature-stable MnIII–alkylperoxo complexes

Published:2021 Issue:38 Volume:12 Page:12564-12575
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Opalade Adedamola A.¹,Parham Joshua D.¹,Day Victor W.¹,Jackson Timothy A.¹^ORCID

Affiliation:

1. The University of Kansas, Department of Chemistry, Center for Environmentally Beneficial Catalysis, 1567 Irving Hill Road, Lawrence, KS 66045, USA

Abstract

A pair of room-temperature-stable MnIII–alkylperoxo complexes were characterized and shown to oxidize PPh3. Thermal decomposition studies provide evidence of both homolysis and heterolysis of the MnIII–alkylperoxo O–O bond.

Funder

National Institute of General Medical Sciences

Directorate for Mathematical and Physical Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01976G

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