Electronic structure contributions to O–O bond cleavage reactions for Mn<sup>III</sup>-alkylperoxo complexes-Reference-Cited by-同舟云学术

Electronic structure contributions to O–O bond cleavage reactions for Mn^III-alkylperoxo complexes

Published:2023 Issue:39 Volume:52 Page:13878-13894
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Brunclik Samuel A.¹^ORCID,Opalade Adedamola A.¹,Jackson Timothy A.¹^ORCID

Affiliation:

1. The University of Kansas, Department of Chemistry and Center for Environmentally Beneficial Catalysis, 1567 Irving Hill Road, Lawrence, KS 66045, USA

Abstract

Through the use of density functional theory calculations and comparisons with published experimental data, the differences in the decay pathways of the MnIII-alkylperoxo complexes [MnIII(OOtBu)(6Medpaq)]+ and [MnIII(OOtBu)(N4S)]+ are rationalized.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01672B

Reference51 articles.

1. Artificial nonheme iron and manganese oxygenases for enantioselective olefin epoxidation and alkane hydroxylation reactions

2. Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond

3. Rational Design of Bioinspired Catalysts for Selective Oxidations

4. Recent advances and perspectives in manganese-catalyzed C–H activation

5. Recent Trends and Prospects in Homogeneous Manganese‐Catalysed Epoxidation

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Investigating Ligand Sphere Perturbations on MnIII–Alkylperoxo Complexes;Molecules;2024-04-18