Oxidative <i>versus</i> basic asynchronous hydrogen atom transfer reactions of Mn(<scp>iii</scp>)-hydroxo and Mn(<scp>iii</scp>)-aqua complexes-Reference-Cited by-同舟云学术

Oxidative versus basic asynchronous hydrogen atom transfer reactions of Mn(iii)-hydroxo and Mn(iii)-aqua complexes

Published:2022 Issue:13 Volume:9 Page:3233-3243
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhang Jisheng¹^ORCID,Lee Yong-Min¹^ORCID,Seo Mi Sook¹^ORCID,Kim Youngsuk²^ORCID,Lee Eunsung²^ORCID,Fukuzumi Shunichi¹³^ORCID,Nam Wonwoo¹^ORCID

Affiliation:

1. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea

2. Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Korea

3. Faculty of Science and Engineering, Meijo University, Nagoya, Aichi 468-8502, Japan

Abstract

This study provides valuable insights into the oxidative vs. basic asynchronous CPET mechanisms of HAT reactions to exhibit reversed electronic substitution effects on HAT reactions of Mn(iii)-hydroxo and Mn(iii)-aqua complexes.

Funder

Japan Society for the Promotion of Science

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00741J

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