Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautiful structures and diverse magnetic properties

Author:

Stamatatos Theocharis C.12345ORCID,Rentschler Eva6789

Affiliation:

1. Department of Chemistry

2. 1812 Sir Isaac Brock Way

3. Brock University

4. L2S 3A1 St. Catharines

5. Canada

6. Institute of Inorganic and Analytical Chemistry

7. Johannes Gutenberg University Mainz

8. D-55128 Mainz

9. Germany

Abstract

A new synthetic route to structurally novel and magnetically interesting 3d-metal azido clusters and coordination polymers is presented; the key reagent for the preparation of solely azido-bridged molecule-based species is the organic azide precursor Me3SiN3.

Funder

Brock University

Ministry of Research and Innovation

Natural Sciences and Engineering Research Council of Canada

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference132 articles.

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4. Magnetic Molecular Conductors

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