Peripheral site modification in a family of dinuclear [Dy2(hynad)2–6(NO3)0–6(sol)0–2]0/2− single-molecule magnets bearing a {Dy2(μ-OR)2}4+ diamond-shaped core and exhibiting dissimilar magnetic dynamics-Reference-Cited by-同舟云学术

Peripheral site modification in a family of dinuclear [Dy₂(hynad)_2–6(NO₃)_0–6(sol)_0–2]^0/2− single-molecule magnets bearing a {Dy₂(μ-OR)₂}⁴⁺ diamond-shaped core and exhibiting dissimilar magnetic dynamics

Published:2023 Issue:38 Volume:52 Page:13565-13577
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Armenis Alexandros S.¹,Alexandropoulos Dimitris I.²,Worrell Anne³,Cunha-Silva Luís⁴^ORCID,Dunbar Kim R.²,Stamatatos Theocharis C.¹⁵^ORCID

Affiliation:

1. Department of Chemistry, University of Patras, 26504 Patras, Greece

2. Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA

3. Department of Chemistry, 1812 Sir Isaac Brock Way, Brock University, L2S 3A1 St Catharines, Ontario, Canada

4. LAQV/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal

5. Institute of Chemical Engineering Sciences, Foundation for Research and Technology – Hellas (FORTH/ICE – HT), Platani, P.O. Box 1414, 26504, Patras, Greece

Abstract

A new family of four dinuclear DyIII complexes bearing the same {Dy2(μ-OR)2}4+ core but different peripheral ligands has been isolated; all complexes exhibit slow relaxation of their magnetization and SMM properties.

Funder

Fundação para a Ciência e a Tecnologia

Ministério da Ciência, Tecnologia e Ensino Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02596A

Reference71 articles.

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4. A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

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