Heterometallic clusters based on an uncommon asymmetric “V-shaped” [Fe3+(μ-OR)Ln3+(μ-OR)2Fe3+]6+ (Ln = Gd, Tb, Dy, Ho) structural core and the investigation of the slow relaxation of the magnetization behaviour of the [Fe2Dy] analogue

Author:

Savva Maria1,Alexandropoulos Dimitris I.1ORCID,Pissas Michael2,Perlepes Spyros P.3ORCID,Papatriantafyllopoulou Constantina1ORCID,Sanakis Yiannis2,Tasiopoulos Anastasios J.1ORCID

Affiliation:

1. Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus

2. Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, 15341 Aghia Paraskevi, Athens, Greece

3. Department of Chemistry, University of Patras, 26504 Patras, Greece

Abstract

A new family of heterometallic [FeIII2Ln] (Ln = Gd, Tb, Dy, Ho) complexes, possessing an uncommon asymmetric “V-shaped” core and interesting magnetic properties is reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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