Coordination of azol(in)ium dithiocarboxylate ligands to Au(<scp>iii</scp>): unexpected formation of a novel family of cyclometallated Au(<scp>iii</scp>) complexes, DFT calculations and catalytic studies-Reference-Cited by-同舟云学术

Coordination of azol(in)ium dithiocarboxylate ligands to Au(iii): unexpected formation of a novel family of cyclometallated Au(iii) complexes, DFT calculations and catalytic studies

Published:2024 Issue:22 Volume:53 Page:9433-9440
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pérez-Ramos Paula¹,Mateo María A.¹,Elorriaga David¹^ORCID,García-Vivó Daniel¹^ORCID,Soengas Raquel G.¹^ORCID,Rodríguez-Solla Humberto¹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica and Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain

Abstract

We describe the preparation and characterization of novel Au(iii) cyclometallated κ1S-azoli(ni)um-2-dithiocarboxylatecomplexes and their rearrangement to Au(iii) biscyclometallated κ2-S,S′-azoli(ni)um-2-(methoxy)methanedithiolate complexes.

Funder

Instituto de Salud Carlos III

Ministerio de Economía y Competitividad

Instituto de Salud Global de Barcelona

European Commission

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01184H

Reference56 articles.

1. Relativistic effects in homogeneous gold catalysis

2. Gold-Catalyzed Organic Transformations

3. Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions

4. A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior

5. Gold Complexes in Anticancer Therapy: From New Design Principles to Particle‐Based Delivery Systems

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. In the search for new gold metalloantibiotics: In vitro evaluation of Au(III) (C^S)-cyclometallated complexes;Journal of Inorganic Biochemistry;2025-01

2. Homoleptic ruthenium(ii) complexes bearing imidazol(in)ium-2-dithiocarboxylate ligands: synthesis, characterization, and redox properties;Dalton Transactions;2024