A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior-Reference-Cited by-同舟云学术

A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior

Published:2020 Issue:20 Volume:49 Page:6561-6565
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ruiz Javier¹²³⁴⁵^ORCID,Sol Daniel¹²³⁴⁵,Mateo María A.¹²³⁴⁵,Vivanco Marilín¹²³⁴⁵,Badía-Laiño Rosana⁶²³⁴⁵

Affiliation:

1. Departamento de Química Orgánica e Inorgánica

2. Facultad de Química

3. Universidad de Oviedo

4. 33006 Oviedo

5. Spain

6. Departamento de Química Física y Analítica

Abstract

Triangular gold(i) N-arylimidazolate clusters have been prepared by a pNHC metalation protocol and their photoluminescence has been switched on by the addition of Ag⁺.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Universidad de Oviedo

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01246G

Reference28 articles.

1. CYCLIC TRINUCLEAR GOLD(I) COMPOUNDS: SYNTHESIS, STRUCTURES AND SUPRAMOLECULAR ACID-BASE π-STACKS

2. Aurophilicity-Triggered Assembly of Novel Cyclic Penta- and Hexanuclear Gold(I) Complexes with Rigid Anionic NHC-Type Ligands

3. Electronic structure of triangular trigold(I) complexes. A theoretical study

4. The first sandwich silver cluster of a trinuclear cyclic gold(I) complex

5. Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching TlI and AgI. Structures of {Ag([Au(μ-C2,N3-bzim)]3)2}BF4·CH2Cl2, {Tl([Au(μ-C2,N3-bzim)]3)2}PF6·0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(μ-C(OEt)═NC6H4CH3)]3)2}PF6·THF, with MAu6 (M = Ag+, Tl+) Cluster Cores

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