Homoleptic ruthenium(<scp>ii</scp>) complexes bearing imidazol(in)ium-2-dithiocarboxylate ligands: synthesis, characterization, and redox properties-Reference-Cited by-同舟云学术

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Homoleptic ruthenium(ii) complexes bearing imidazol(in)ium-2-dithiocarboxylate ligands: synthesis, characterization, and redox properties

Published:2024 Issue:27 Volume:53 Page:11436-11444
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Carvalho Valdemiro P.¹^ORCID,Zaragoza Guillermo²,Delaude Lionel¹^ORCID

Affiliation:

1. Laboratory of Catalysis, MolSys Research Unit, Institut de Chimie Organique (B6a), Allée du six Août 13, Université de Liège, 4000 Liège, Belgium

2. Unidade de Difracción de Raios X, RIAIDT, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, Spain

Abstract

Five homoleptic ruthenium(ii) chelates with the generic formula [Ru(S2C·NHC)3](PF6)2 were synthesized and fully characterized. Their redox properties were investigated by cyclic voltammetry. They displayed a remarkable stability in solution.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01503G

Reference41 articles.

1. Betaine Adducts of N‐Heterocyclic Carbenes: Synthesis, Properties, and Reactivity

2. Concave Imidazolinium Salts as Precursors to Concave N-Heterocyclic Carbenes

3. Enantiopure imidazolinium-dithiocarboxylates as highly selective novel organocatalysts

4. Carbene-Mediated Transformations of 1-(Benzylideneamino)benzimidazoles

5. Fine-Tunable 3,4-Dihydroquinazol-2-ylidene Carbenes: Synthesis, Rhodium(I) Complexes, and Reactivity

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