Barrierless tautomerization of Criegee intermediates via acid catalysis-Reference-Cited by-同舟云学术

Barrierless tautomerization of Criegee intermediates via acid catalysis

Published:2014 Issue:42 Volume:16 Page:22968-22973
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kumar Manoj¹²³⁴⁵,Busch Daryle H.¹²³⁴⁵,Subramaniam Bala⁴⁵⁶⁷²,Thompson Ward H.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. University of Kansas

3. Lawrence 66045, USA

4. Center for Environmentally Beneficial Catalysis

5. 1501 Wakarusa Drive

6. Lawrence, USA

7. Department of Chemical and Petroleum Engineering

Abstract

Electronic structure calculations indicate that the organic acids catalyze the tautomerization of Criegee intermediates via a 1,4 β-hydrogen atom transfer to yield a vinyl hydroperoxide to such an extent that it becomes a barrierless process.

Funder

National Institute of Food and Agriculture

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP03065F

Reference60 articles.

1. Direct Kinetic Measurements of Criegee Intermediate (CH 2 OO) Formed by Reaction of CH 2 I with O 2

2. Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH 3 CHOO

3. Mechanism of Ozonolysis

4. Safe Execution of a Large-Scale Ozonolysis: Preparation of the Bisulfite Adduct of 2-Hydroxyindan-2-carboxaldehyde and Its Utility in a Reductive Amination

5. Ozonolysis of Vinylpyridines

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