Direct Kinetic Measurements of Criegee Intermediate (CH 2 OO) Formed by Reaction of CH 2 I with O 2

Abstract

Criegee Sighting Standard mechanistic models for the reaction of ozone with unsaturated hydrocarbons implicate a transient carbonyl oxide compound, termed the “Criegee intermediate,” which has largely eluded detection. Welz et al. (p. 204 ; see the Perspective by Marston ) have now detected the compound by using mass spectrometry, following the low-pressure photolytic reaction of oxygen with diiodomethane, and measured its decay kinetics in the presence of nitric oxide, nitrogen dioxide, and sulfur dioxide. Reaction rates were higher than expected, suggesting that the intermediate may play a more prominent role in atmospheric chemistry than previously assumed.