Experimental and theoretical studies on gold(iii) carbonyl complexes: reductive C,H- and C,C bond formation-Reference-Cited by-同舟云学术

Experimental and theoretical studies on gold(iii) carbonyl complexes: reductive C,H- and C,C bond formation

Published:2021 Issue:25 Volume:50 Page:8752-8760
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ahrens Alexander¹²³⁴^ORCID,Lustosa Danilo M.¹²³⁴⁵,Karger Leonhard F. P.¹²³⁴,Hoffmann Marvin⁵²³⁴,Rudolph Matthias¹²³⁴,Dreuw Andreas⁵²³⁴^ORCID,Hashmi A. Stephen K.¹²³⁴^ORCID

Affiliation:

1. Organisch-Chemisches Institut

2. Heidelberg University

3. 69120 Heidelberg

4. Germany

5. Interdisciplinary Center for Scientific Computing (IWR)

Abstract

Transient cationic (C^C)gold(iii) carbonyls act as electrophiles, leading either to reductive C,H bond formation via a water-gas-shift-type reaction or a reductive C,C bond formation via a gold(iii) carboxylate.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01315G

Reference52 articles.

1. Nonclassical Metal Carbonyls: Appropriate Definitions with a Theoretical Justification

2. How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes

3. Bis(carbonyl)gold(I) undecafluorodiantimonate(V), [Au(CO)2][Sb2F11]: synthesis, vibrational, and carbon-13 NMR study and the molecular structure of bis(acetonitrile)gold(I) hexafluoroantimonate(V), [Au(NCCH3)2][SbF6]