Energetics of key Au(<scp>iii</scp>)-substrate adducts relevant to catalytic hydroarylation of alkynes-Reference-Cited by-同舟云学术

Energetics of key Au(iii)-substrate adducts relevant to catalytic hydroarylation of alkynes

Published:2023 Issue:38 Volume:52 Page:13528-13536
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Regnacq Matthieu¹,Lesage Denis¹,Holmsen Marte S. M.²³⁴,Miqueu Karinne⁵^ORCID,Bourissou Didier²^ORCID,Gimbert Yves¹⁶

Affiliation:

1. Institut Parisien de Chimie Moléculaire – IPCM UMR 8232, CNRS/Sorbonne Université, 75252 Paris Cedex 05, France

2. Laboratoire Hétérochimie Fondamentale et Appliquée – LHFA UMR 5069, CNRS/Université de Toulouse, UPS, 31062 Toulouse Cedex 09, France

3. Centre for Materials Science and Nanotechnology, University of Oslo, P.O. Box 1126 Blindern, N-0316 Oslo, Norway

4. Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo, Norway

5. CNRS/Université de Pau et des Pays de l'Adour, E2S-UPPA, Institut des Sciences Analytiques et de Physico-Chimie pour l'Environnement et les Matériaux – IPREM UMR 5254, 64053 Pau Cedex 09, France

6. Département de Chimie Moléculaire – DCM UMR 5250, CNRS/Université Grenoble Alpes, UGA, 38000 Grenoble, France

Abstract

(P,C)-cyclometalated Au(iii) complexes have shown remarkable ability to catalyze the intermolecular hydroarylation of alkynes.

Funder

Agence Nationale de la Recherche

Norges Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02393A

Reference40 articles.

1. Cyclometalated Gold(III) Complexes: Synthesis, Reactivity, and Physicochemical Properties

2. Recent Advances in Gold(III) Chemistry: Structure, Bonding, Reactivity, and Role in Homogeneous Catalysis

3. Catalytic Activity of trans-Bis(pyridine)gold Complexes

4. Mechanism of Au(III)-Mediated Alkoxycyclization of a 1,6-Enyne

5. Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity

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