How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes-Reference-Cited by-同舟云学术

How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes

Published:2016 Issue:2 Volume:7 Page:1174-1184
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bistoni Giovanni¹²³⁴⁵^ORCID,Rampino Sergio⁶⁴⁵^ORCID,Scafuri Nicola⁷⁸⁹¹⁰,Ciancaleoni Gianluca⁶⁴⁵^ORCID,Zuccaccia Daniele¹¹¹¹²⁵^ORCID,Belpassi Leonardo⁶⁴⁵^ORCID,Tarantelli Francesco¹²³⁴⁵^ORCID

Affiliation:

1. Dipartimento di Chimica

2. Biologia e Biotecnologie

3. Università di Perugia

4. 06123 Perugia

5. Italy

6. Istituto di Scienze e Tecnologie Molecolari del CNR

7. Institut Charles Gerhardt

8. Université Moltpellier 2

9. 34095 Montpellier Cedex 5

10. France

11. Fisica e Ambiente

12. 33100 Udine

Abstract

We definitively show that the CO stretching response to metal coordination is driven exclusively by π polarization, which quantitatively correlates with π back-donation and changes in CO bond length and frequency.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC02971F

Reference74 articles.

1. Synthetic and Mechanistic Aspects of Inorganic Insertion Reactions. Insertion of Carbon Monoxide

2. Kinetic studies of CO substitution of metal carbonyls in the presence of O-atom transfer reagents

3. Catalysis in C1 chemistry: Future and prospect

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