A practical, catalytic and selective deprotection of a Boc group in N,N′-diprotected amines using iron(iii)-catalysis
Author:
Affiliation:
1. Instituto Universitario de Bio-Orgánica “Antonio González”
2. CIBICAN
3. Universidad de La Laguna
4. La Laguna
5. Spain
Abstract
A selective, catalytic and practical method for removing a Boc group from several N,N′-diprotected amino acids and amine derivatives using iron(iii) salts as sustainable catalysts is described.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA12143K
Reference18 articles.
1. Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?
2. Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions
3. Sustainability in Catalysis - Concept or Contradiction?
4. T. W. Greene and P. G. M.Wuts, Protective Groups in organic Synthesis, John Wiley & Sons, New York, 3rd edn, 1999 and references cited therein
5. Simple and efficient cleavage reaction of the boc group in heterocyclic compounds
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