Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization-Reference-Cited by-同舟云学术

Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization

Published:2020 Issue:46 Volume:11 Page:12436-12445
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Salvadori Enrico¹²³⁴^ORCID,Chiesa Mario¹²³⁴^ORCID,Buonerba Antonio⁵⁶⁷⁴^ORCID,Grassi Alfonso⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Turin

3. Torino 10125

4. Italy

5. Dipartimento di Chimica e Biologia

6. Università degli Studi di Salerno

7. I-84084 Fisciano

Abstract

Catalytically competent titanium-hydrides are reactive and difficult to isolate. We use EPR spectroscopy to define the electronic and geometrical structures as well as dynamics of an open-shell Ti-H active in syndiospecific olefin polymerization.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04967K

Reference68 articles.

1. Direct Detection of a Hydrogen Ligand in the [NiFe] Center of the Regulatory H2-Sensing Hydrogenase from Ralstonia eutropha in Its Reduced State by HYSCORE and ENDOR Spectroscopy

2. Trapping H- Bound to the Nitrogenase FeMo-Cofactor Active Site during H2 Evolution: Characterization by ENDOR Spectroscopy

3. Selective Hydrogenation for Fine Chemicals: Recent Trends and New Developments

4. Catalytic hydrocyanation of olefins by nickel(0) phosphite complexes - effects of Lewis acids

5. Asymmetric Hydroformylation

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Porous oligomeric materials synthesised using a new, highly active precatalyst based on ruthenium(iii) and 2-phenylpyridine;Dalton Transactions;2024

2. Photo‐Induced Radicals in Carbon Nitride and their Magnetic Signature;ChemPhotoChem;2023-12-07

3. A primer in pulse EPR-based hyperfine spectroscopy for NMR spectroscopists;Journal of Magnetic Resonance Open;2023-12

4. Oxo‐Bridged Zr Dimers as Well‐defined Models of Oxygen Vacancies on ZrO₂;European Journal of Inorganic Chemistry;2023-02-28

5. Synthesis and Tuning of Gold Nanoparticles Supported on Polymorphic Semicrystalline Nanoporous Polymer for Catalytic Aerobic Oxidation of Alcohols;European Journal of Inorganic Chemistry;2022-10-31