Direct Detection of a Hydrogen Ligand in the [NiFe] Center of the Regulatory H2-Sensing Hydrogenase from Ralstonia eutropha in Its Reduced State by HYSCORE and ENDOR Spectroscopy-Reference-Cited by-同舟云学术

Direct Detection of a Hydrogen Ligand in the [NiFe] Center of the Regulatory H2-Sensing Hydrogenase from Ralstonia eutropha in Its Reduced State by HYSCORE and ENDOR Spectroscopy

Published:2003-10-01 Issue:43 Volume:125 Page:13075-13083
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Brecht Marc¹,van Gastel Maurice¹,Buhrke Thorsten¹,Friedrich Bärbel¹,Lubitz Wolfgang¹

Affiliation:

1. Contribution from the Max-Volmer-Laboratorium für Biophysikalische Chemie, Fakultät für Mathematik und Naturwissenschaften, Technische Universität Berlin, D-10623 Berlin, Germany; Max-Planck-Institut für Bioanorganische Chemie, P.O. Box 101365, D-45413 Mülheim an der Ruhr, Germany; and Institut für Biologie, Humboldt-Universität Berlin, D-10115 Berlin, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja036624x

Reference44 articles.

1. Classification and phylogeny of hydrogenases

2. Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas

3. Unusual ligand structure in Ni–Fe active center and an additional Mg site in hydrogenase revealed by high resolution X-ray structure analysis

4. Removal of the bridging ligand atom at the Ni–Fe active site of [NiFe] hydrogenase upon reduction with H2, as revealed by X-ray structure analysis at 1.4 Å resolution

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