An environmentally benign way to synthesize 2-thiocyano-1,3-dicarbonyl compounds with high antifungal activity: a key role of solvent-Reference-Cited by-同舟云学术

An environmentally benign way to synthesize 2-thiocyano-1,3-dicarbonyl compounds with high antifungal activity: a key role of solvent

Published:2023 Issue:17 Volume:21 Page:3615-3622
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kirillov Andrey S.¹,Semenov Egor A.¹,Bityukov Oleg V.¹,Kuznetsova Maria A.²^ORCID,Demidova Valentina N.²^ORCID,Rogozhin Alexander N.²,Glinushkin Alexei P.²,Vil’ Vera A.¹^ORCID,Terent'ev Alexander O.¹^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

2. All-Russian Research Institute for Phytopathology, B. Vyazyomy, 143050, Moscow Region, Russian Federation

Abstract

The electrochemical synthesis of fungicidal thiocyanates from 1,3-dicarbonyl compounds and ammonium thiocyanate was developed. The high efficiency of electrochemical thiocyanation was only achieved using AcOH as the solvent.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB00474K

Reference100 articles.

1. The Isolation and Synthesis of Novel Nematocidal Dithiocyanates from an Australian Marine Sponge, Oceanapia sp.

2. DNA Damage by Fasicularin

3. Design, Synthesis, and Biological Evaluation of Aryloxyethyl Thiocyanate Derivatives against Trypanosoma cruzi