Electrochemical synthesis of CN-substituted imidazo[1,5-a]pyridines via a cascade process using NH4SCN as both an electrolyte and a non-trivial cyanating agent-Reference-Cited by-同舟云学术

Electrochemical synthesis of CN-substituted imidazo[1,5-a]pyridines via a cascade process using NH₄SCN as both an electrolyte and a non-trivial cyanating agent

Published:2024 Issue:2 Volume:11 Page:327-335
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Grishin Sergei S.¹²,Mulina Olga M.¹^ORCID,Vil’ Vera A.¹^ORCID,Terent'ev Alexander O.¹²^ORCID

Affiliation:

1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow, 119991, Russian Federation

2. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Square, 125047, Moscow, Russian Federation

Abstract

An electrochemical cascade of oxidation/cyclization of pyridine-2-carboxaldehydes with benzylamines involving in situ cyanation with NH4SCN to afford 1-cyano-imidazo[1,5-a]pyridines was developed.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D3QO01690K

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