The kinetics and mechanism of the organo-iridium catalysed racemisation of amines-Reference-Cited by-同舟云学术

The kinetics and mechanism of the organo-iridium catalysed racemisation of amines

Author:

Stirling Matthew J.¹²³⁴⁵,Mwansa Joseph M.¹²³⁴⁵,Sweeney Gemma¹²³⁴⁵,Blacker A. John⁶⁷⁸⁹⁵,Page Michael I.¹²³⁴⁵

Affiliation:

1. IPOS

2. Department of Chemical Sciences

3. The University of Huddersfield

4. Huddersfield HD1 3DH

5. UK

6. Institute of Process Research & Development

7. School of Chemistry

8. University of Leeds

9. Leeds

Abstract

The iridium complex [IrCp*I₂]₂ catalyses the racemisation of amines with a low catalyst loading by rate-limiting hydride transfer.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

Reference37 articles.

2. Pharmaceutical Salts and Co-crystals, ed. J. Wouters and L. Quere, RSC Publishing, 2011

5. Comprehensive Asymmetric Catalysis, ed. E. N. Jacobsen, A. Pfaltz and H. Yamamoto, Springer, London, 1999

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