Carboxamide substituted tetramethylcyclopentadiene – synthesis, characterisation and its iridium(<scp>iii</scp>) complex catalysed reduction of imines-Reference-Cited by-同舟云学术

Carboxamide substituted tetramethylcyclopentadiene – synthesis, characterisation and its iridium(iii) complex catalysed reduction of imines

Published:2022 Issue:7 Volume:51 Page:2696-2707
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mwansa Joseph M.¹^ORCID,Stirling Matthew J.²,Sweeney Gemma³,Hanusek Jiří⁴^ORCID,Váňa Jiří⁴^ORCID,Page Michael I.¹^ORCID

Affiliation:

1. School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, UK

2. Analytical Innovations, Shaw Park, Huddersfield HD5 9AG

3. University of Huddersfield, Queensgate, Huddersfield HD1 3DH

4. Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentska 573, CZ 532 10 Pardubice, The Czech Republic

Abstract

The novel dimeric iodo-iridium(iii) complex bearing an amide moiety within the tetramethylcyclopentadiene ring, has been synthesised, characterised and its catalytic activity has been evaluated in the transfer hydrogenation of imines.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00149G

Reference25 articles.

1. Catalysis, kinetics and mechanisms of organo-iridium enantioselective hydrogenation-reduction

2. The kinetics and mechanism of the organo-iridium-catalysed enantioselective reduction of imines

3. Acceleration Mechanisms of C–H Bond Functionalization Catalyzed by Electron-Deficient CpRh(III) Complexes

4. Changing the kinetic order of enantiomer formation and distinguishing between iminium ion and imine as the reactive species in the asymmetric transfer hydrogenation of substituted imines using a cyclopentadienyl iridium (III) complex

5. Kinetic Studies of the Asymmetric Transfer Hydrogenation of Imines with Formic Acid Catalyzed by Rh−Diamine Catalysts