Efficient (<i>Z</i>)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides-Reference-Cited by-同舟云学术

Efficient (Z)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides

Published:2023 Issue:6 Volume:10 Page:1786-1794
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Gutiérrez-Blanco María¹^ORCID,Guillamón Eva¹,Safont Vicent S.¹^ORCID,Algarra Andrés G.²^ORCID,Fernández-Trujillo M. Jesús²,Junge Kathrin³^ORCID,Basallote Manuel G.²^ORCID,Llusar Rosa¹^ORCID,Beller Matthias³^ORCID

Affiliation:

1. Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071 Castelló, Spain

2. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Instituto de Biomoléculas (INBIO), Facultad de Ciencias, Universidad de Cádiz, Apartado 40, Puerto Real, 11510 Cádiz, Spain

3. Leibniz-Institute for Catalysis, Albert-Einstein-Street 29a, 18059 Rostock, Germany

Abstract

Efficient protocols for the semihydrogenation of internal alkynes and terminal alkynols are reported using the new [Mo3S4Cl3(ImNH2)3]+ complex as catalyst.

Funder

Generalitat Valenciana

Ministerio de Economía y Competitividad

Universitat Jaume I

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02755K

Reference32 articles.

1. Modern Trends in Catalyst and Process Design for Alkyne Hydrogenations

2. New developments in hydrogenation catalysis particularly in synthesis of fine and intermediate chemicals

3. Ein neuer Katalysator für selektive Hydrierungen

4. Homogeneous catalytic transfer semihydrogenation of alkynes – an overview of hydrogen sources, catalysts and reaction mechanisms

5. Chemoselective semihydrogenation of alkynes catalyzed by manganese(i)-PNP pincer complexes

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2. Selective Dehydrogenation of Formic Acid Catalyzed by Air‐Stable Cuboidal PN Molybdenum Sulfide Clusters;ChemCatChem;2023-10-02