Efficient (<i>Z</i>)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides-Reference-Cited by-同舟云学术

Efficient (Z)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides

Published:2023 Issue:6 Volume:10 Page:1786-1794
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Gutiérrez-Blanco María¹^ORCID,Guillamón Eva¹,Safont Vicent S.¹^ORCID,Algarra Andrés G.²^ORCID,Fernández-Trujillo M. Jesús²,Junge Kathrin³^ORCID,Basallote Manuel G.²^ORCID,Llusar Rosa¹^ORCID,Beller Matthias³^ORCID

Affiliation:

1. Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071 Castelló, Spain

2. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Instituto de Biomoléculas (INBIO), Facultad de Ciencias, Universidad de Cádiz, Apartado 40, Puerto Real, 11510 Cádiz, Spain

3. Leibniz-Institute for Catalysis, Albert-Einstein-Street 29a, 18059 Rostock, Germany

Abstract

Efficient protocols for the semihydrogenation of internal alkynes and terminal alkynols are reported using the new [Mo3S4Cl3(ImNH2)3]+ complex as catalyst.

Funder

Generalitat Valenciana

Ministerio de Economía y Competitividad

Universitat Jaume I

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02755K

Reference32 articles.

1. Modern Trends in Catalyst and Process Design for Alkyne Hydrogenations