Homogeneous catalytic transfer semihydrogenation of alkynes – an overview of hydrogen sources, catalysts and reaction mechanisms-Reference-Cited by-同舟云学术

Homogeneous catalytic transfer semihydrogenation of alkynes – an overview of hydrogen sources, catalysts and reaction mechanisms

Published:2020 Issue:19 Volume:10 Page:6449-6463
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Decker David¹²³,Drexler Hans-Joachim¹²³^ORCID,Heller Detlef¹²³,Beweries Torsten¹²³^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V. (LIKAT)

2. 18059 Rostock

3. Germany

Abstract

Chemoselective semihydrogenation of alkynes to alkenes with E- or Z-stereoselectivity is among the most important transformations in the synthesis of highly functional organic building blocks.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY01276A

Reference105 articles.

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2. We would like to note that examples for transition metal-free selective SH of alkynes are known, however, these will not be discussed in this review

3. Selected overviews: W.Bonrath , J. A.Medlock and M.-A.Müller , Catalytic Reduction of Alkynes and Allenes, in Catalytic Reduction in Organic Synthesis 1, 2018 , ed. J. G. de Vries , Georg Thieme Verlag , Stuttgart , 2018

4. Advances in chemoselective and/or stereoselective semihydrogenation of alkynes

5. Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough To Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules?

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