Spin-Crossing in the (Z)-Selective Alkyne Semihydrogenation Mechanism Catalyzed by Mo3S4 Clusters: A Density Functional Theory Exploration-Reference-Cited by-同舟云学术

Spin-Crossing in the (Z)-Selective Alkyne Semihydrogenation Mechanism Catalyzed by Mo₃S₄ Clusters: A Density Functional Theory Exploration

Published:2024-01-04 Issue:2 Volume:63 Page:1000-1009
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Gutiérrez-Blanco María¹^ORCID,Algarra Andrés G.²^ORCID,Guillamón Eva¹^ORCID,Fernández-Trujillo M. Jesús²,Oliva Mónica¹^ORCID,Basallote Manuel G.²^ORCID,Llusar Rosa¹^ORCID,Safont Vicent S.¹

Affiliation:

1. Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, Castelló 12071, Spain

2. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Instituto de Biomoléculas (INBIO), Facultad de Ciencias, Universidad de Cádiz, Apartado 40, Puerto Real, Cádiz 11510, Spain

Funder

Generalitat Valenciana

Universitat Jaume I

Ministerio de Ciencia e Innovación

Ministerio de Economía y Competitividad

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.3c03057

Reference52 articles.

1. Advances in chemoselective and/or stereoselective semihydrogenation of alkynes

2. Selective Hydrogenation for Fine Chemicals: Recent Trends and New Developments

3. Activation of dihydrogen and coordination of molecular H2 on transition metals

4. Chemoselective semihydrogenation of alkynes catalyzed by manganese(i)-PNP pincer complexes

5. Balancing the Seesaw in Mn-Catalyzed N-Heteroarene Hydrogenation: Mechanism-Inspired Catalyst Design for Simultaneous Taming of Activation and Transfer of H₂