Conservation of direct dynamics in sterically hindered SN2/E2 reactions-Reference-Cited by-同舟云学术

Conservation of direct dynamics in sterically hindered SN2/E2 reactions

Published:2018 Issue:3 Volume:9 Page:693-701
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Carrascosa Eduardo¹²³⁴^ORCID,Meyer Jennifer¹²³⁴^ORCID,Michaelsen Tim¹²³⁴,Stei Martin¹²³⁴,Wester Roland¹²³⁴^ORCID

Affiliation:

1. Institut für Ionenphysik und Angewandte Physik

2. Universität Innsbruck

3. 6020 Innsbruck

4. Austria

Abstract

The effect of steric hindrance on the stereodynamics of nucleophilic substitution (S_N2) and base-induced elimination (E2) has been studied using crossed-beam velocity map imaging.

Funder

Austrian Science Fund

Austrian Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04415A

Reference45 articles.

1. M. B. Smith and J.March , March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure , John Wiley & Sons , 2007

2. Gas-Phase Ionic Reactions: Dynamics and Mechanism of Nucleophilic Displacements

3. Gas-phase nucleophilic displacement reactions

4. Trajectory studies of SN2 nucleophilic substitution. III. Dynamical stereochemistry and energy transfer pathways for the Cl−+CH3Cl association and direct substitution reactions

5. Simulations of Gas-Phase Chemical Reactions: Applications to S N 2 Nucleophilic Substitution

Cited by 34 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Competing C and N as Reactive Centers for Microsolvated Ambident Nucleophiles CN^–(H₂O)_n=0–3: A Theoretical Study of E2/S_N2 Reactions with CH₃CH₂X (X = Cl, Br, I);The Journal of Physical Chemistry A;2024-05-31

2. Ion molecule reaction dynamics for disentangling competing reactive pathways;Molecular Physics;2024-01-09

3. Reaction dynamics of the methoxy anion CH₃O⁻ with methyl iodide CH₃I;Faraday Discussions;2024

4. Solvent-induced dual nucleophiles and the α-effect in the S_N2 versus E2 competition;Physical Chemistry Chemical Physics;2024

5. Competition between Elimination and Substitution for Ambident Nucleophiles CN^– and Iodoethane Reactions in Gaseous and Aqueous Medium;The Journal of Physical Chemistry A;2023-08-28