Reaction dynamics of the methoxy anion CH3O− with methyl iodide CH3I-Reference-Cited by-同舟云学术

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Reaction dynamics of the methoxy anion CH₃O⁻ with methyl iodide CH₃I

Published:2024 Issue: Volume:251 Page:573-586
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Gstir Thomas¹^ORCID,Sundelin David²,Michaelsen Tim¹,Ayasli Atilay¹,Swaraj Dasarath¹,Judy Jerin¹,Zappa Fabio¹^ORCID,Geppert Wolf²,Wester Roland¹^ORCID

Affiliation:

1. Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, 6020 Innsbruck, Austria

2. Department of Physics, Stockholm University, 106 91 Stockholm, Sweden

Abstract

Studying nucleophilic substitution reactions of the polyatomic methoxy anion allows us to narrow the gap to the large systems used in organic synthesis. Despite its complexity, we find predominantly direct dynamics at all studied collision energies.

Funder

Vetenskapsrådet

Austrian Science Fund

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/FD/D3FD00164D

Reference57 articles.

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2. Molecular Beam Studies of Elementary Chemical Processes

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4. Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen

5. Imaging of the charge-transfer reaction of spin–orbit state-selected Ar+(2P3/2) with N2 reveals vibrational-state-specific mechanisms

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